Monolithic integration of room-temperature multifunctional BaTiO3-CoFe2O4 epitaxial heterostructures on Si(001)
نویسندگان
چکیده
The multifunctional (ferromagnetic and ferroelectric) response at room temperature that is elusive in single phase multiferroic materials can be achieved in a proper combination of ferroelectric perovskites and ferrimagnetic spinel oxides in horizontal heterostructures. In this work, lead-free CoFe2O4/BaTiO3 bilayers are integrated with Si(001) using LaNiO3/CeO2/YSZ as a tri-layer buffer. They present structural and functional properties close to those achieved on perovskite substrates: the bilayers are fully epitaxial with extremely flat surface, and exhibit robust ferromagnetism and ferroelectricity at room temperature.
منابع مشابه
Epitaxial integration of perovskite-based multifunctional oxides on silicon
We review recent developments in the epitaxial integration of multifunctional oxide thin film heterostructures on silicon (Si). Perovskite oxides have been extensively studied for use in multifunctional devices due to a wide range of functional properties. To realize multifunctional oxide devices, these multifunctional films should be integrated directly on Si, maintaining high crystalline qual...
متن کاملMultiferroic BaTiO3-CoFe2O4 Nanostructures.
We report on the coupling between ferroelectric and magnetic order parameters in a nanostructured BaTiO3-CoFe2O4 ferroelectromagnet. This facilitates the interconversion of energies stored in electric and magnetic fields and plays an important role in many devices, including transducers, field sensors, etc. Such nanostructures were deposited on single-crystal SrTiO3 (001) substrates by pulsed l...
متن کاملThree-dimensional heteroepitaxy in self-assembled BaTiO3–CoFe2O4 nanostructures
Self-assembled BaTiO3–CoFe2O4 complex oxide nanostructures have been synthesized by pulsed laser deposition. A single ceramic target with a molar ratio of 0.62BaTiO3–0.38CoFe2O4 was used. Spinel CoFe2O4 and perovskite BaTiO3 phases spontaneously separated during heteroepitaxial growth on a single-crystal SrTiO3 s001d substrate. The nanostructures are epitaxial in-plane as well as out-of-plane, ...
متن کاملLocal dielectric measurements of BaTiO3–CoFe2O4 nanocomposites through microwave microscopy
We report on linear and nonlinear dielectric property measurements of BaTiO3–CoFe2O4 (BTO–CFO) ferroelectromagnetic nanocomposites and pure BaTiO3 and CoFe2O4 samples with scanning near-field microwave microscopy. The permitivity scanning image with spatial resolution on the micrometer scale shows that the nanocomposites have a very uniform quality with an effective dielectric constant r 140 ± ...
متن کاملA review of molecular beam epitaxy of ferroelectric BaTiO3 films on Si, Ge and GaAs substrates and their applications
SrTiO3 epitaxial growth by molecular beam epitaxy (MBE) on silicon has opened up the route to the monolithic integration of various complex oxides on the complementary metal-oxide-semiconductor silicon platform. Among functional oxides, ferroelectric perovskite oxides offer promising perspectives to improve or add functionalities on-chip. We review the growth by MBE of the ferroelectric compoun...
متن کامل